An optimization method to find the thermodynamic limit on enhancement of solar thermal decomposition of methane

An optimization approach to enhancing the solar thermal decomposition of methane (TDM) reaction process based on the fluid flow pattern reconstruction is proposed. The sum of entropy generations due to TDM reaction and heat convection in the process is shown to tend to its maximum when the performance of the reaction is enhanced, and thus, is used as the criterial to optimize the velocity field of the fluid. This optimization problem is solved by the calculus of variations method. The obtained flow pattern is shown to be able to give the conditions to achieve the optimally enhanced TDM process. As the sum of the entropy generations tends to its extremum, the solution found by the optimization can be known as the thermodynamic limit for the TDM process enhancement. The obtained flow pattern can then be used to inspire the design of internal structures of the solar TDM reactor.     

Experimental study and kinetic modeling of methane decomposition in a rotating arc plasma reactor with different cross-sectional areas

Methane decomposition into hydrogen and carbon is analyzed in a plasma reactor, with a rotating arc and different cross-sectional areas for the passing gas. This novel setup helps the arc discharge to sweep a larger fraction of the reactant which could cause a better interaction of methane molecules with plasma phase causing higher conversions. The effects of angular velocity of arc discharge, feed flow rate, and cross-sectional area for the passing gas were investigated on the reactor performance. Methane conversion increased significantly by changing the arc mode from stationary to rotating. Increasing the cross-sectional area for the passing gas causes conversion drop for stationary arc whereas a slight increase in conversion is observed for rotating arc mode. Hydrogen production rate of 100 ml/min with an energy yield of 26.8 g/kWh achieved at a methane flow rate of 150 ml/min. The residence time is estimated to be 0.2–3.9 s in the range of the present study, which is a much longer period compared to the plasma process time. Therefore, it is suggested that the mass transfer rate between the gas and plasma phase is the controlling factor for methane conversion. In this respect, an apparent reaction rate constant is derived by considering methane conversion as that fraction of gas, which is exposed to the active area of the plasma arc column.     

铅基快堆关键热工水力问题研究综述

铅基快堆是一种极具发展潜力的第4代核能系统，在燃料增殖和嬗变方面具有独特优势，具有良好的非能动安全特性和经济性，且有利于实现小型化，是目前国际核能领域研究的热点。本文总结了国内外主要铅基堆型，指出了小型化是铅基快堆的发展方向，同时也指出了当前铅基快堆发展所面临的主要问题。针对热工水力关键问题的5个方面，即液态铅/铅铋流动换热特性研究、堆芯/组件热工水力分析、铅池内流动换热现象研究、系统热工水力安全分析以及特殊现象的热工水力分析，对国内外研究现状展开了分析，总结了当前研究成果，并分析了研究的发展趋势以及遇到的技术瓶颈。本文可为铅基快堆的设计和热工水力分析提供一定的建议和指导。     

Comparison of co-current and counter-current flow in a bifunctional reactor containing ammonia synthesis and 2-butanol dehydrogenation to MEK

In this study, a multi-tubular thermally coupled packed bed reactor in which simultaneous production of ammonia and methyl ethyl ketone (MEK) takes place is simulated. The simulation results are presented in two co-current and counter-current flow modes. Based on this new configuration, the released heat from the ammonia synthesis reaction as an extremely exothermic reaction in the inner tube is employed to supply the required heat for the endothermic 2-butanol dehydrogenation reaction in the outer tube. On the other hand, MEK and hydrogen are produced by the dehydrogenation reaction of 2-butanol in the endothermic side, and the produced hydrogen is used to supply a part of the ammonia synthesis feed in the exothermic side. Thus, 30.72% and 31.88% of the required hydrogen for the ammonia synthesis are provided by the dehydrogenation reaction in the co-current and counter-current configurations, respectively. Also, according to the thermal coupling, the required cooler and furnace for the ammonia synthesis and 2-butanol dehydrogenation conventional plants are eliminated, respectively. As a result, operational costs, energy consumption and furnace emissions are considerably decreased. Finally, a sensitivity analysis and optimization are applied to study the effect of the main process parameters variation on the system performance and obtain the minimum hydrogen make-up flow rate, respectively.     

Study of the performance of dry methane reforming in a microchannel reactor using sputtered Ni/Al2O3 coating on stainless steel

In this study, a microchannel reactor was designed, its catalytic performance in dry methane reforming (DRM) was assessed, and the results were compared with those observed in a conventional fixed bed reactor. The catalyst was prepared in two forms, including catalyst pellets and catalyst-coated plate. The microchannel reactor had thin films of Ni/Al₂O₃ coated on stainless steel substrate via radio frequency (RF) magnetron sputtering method in various sputtering times. The fall-off rate of the catalyst-coated plates can be neglected after putting the plates under the high-temperature DRM reaction, due to the formation of firm active catalyst coatings. The performance of the samples was evaluated at different temperatures from 700 to 800 °C, at P = 1 atm, with a CH₄:CO₂ ratio of 1. The results of XRD showed that with increasing the sputtering time, there was an increase in crystallinity. As observed in FESEM images, the sample prepared with 5 min of sputtering was dense and uniform. The results of EDX not only proved the dispersion of the samples observed in XRD and FESEM analysis, but also verified the presence of the utilized elements. The temperature of 800 °C and the sample with 5 min sputtering time were selected as the optimum condition that provided the best performance. Catalytic performance was investigated in fixed bed reactor at the same GHSV; based on the results there were no significant conversions in the fixed bed reactor. The results of the stability test in the microchannel reactor showed a good performance during 30 h on stream. Therefore, Ni/Al₂O₃ thin films had a satisfactory performance in the designed microchannel. Our study shows that this type of reactor has many advantages in terms of performance, compactness, and economic concerns.     

Risks of modular integrated construction: A review and future research directions

Stakeholders remain skeptical in adopting modular integrated construction (MiC) because of the associated risks and uncertainties, although its benefits have been extensively documented. The unique business model of MiC nurtures several risks and uncertainties different from those of the conventional construction approach. Despite the growing attention on MiC with its market expansion, no systematic evaluation is in place to monitor its risks research progress. Accordingly, this research reviewed published literature addressing the risks associated with MiC from 1992 to 2019. Analysis reveals that the research publications on risks of MiC witnessed a steady growth, with considerable progress occurring in the last decade. Result implies that the risk of MiC has gained extra attention in the construction engineering and management domain in recent times. Existing empirical studies have focused heavily on perceived implementation risks, supply chain risks, schedule risks, investment risks, structural risks, ergonomic risks, and MiC risk management strategies, which indicate that MiC is associated with a host of risk events. The research further identified the critical risk events (CREs) in the application of MiC based on frequency of occurrence. The identified CREs contributes to the checklists of risk events in the implementation of offsite construction (OSC). The latter may be useful in risk planning, especially where the MiC is less developed, and fewer or no bespoke risk assessment exists. Research gaps in existing studies are highlighted in this research, and areas for further studies are then proposed. Thus, it makes a useful contribution to the scholarly literature on the risk of OSC and may prove useful to offsite construction researchers, industry practitioners, and project managers.     

Gasification of torrefied oil palm biomass in a fixed-bed reactor: Effects of gasifying agents on product characteristics

Gasification represents an attractive pathway to generate fuel gas (i.e., syngas (H₂ and CO) and hydrocarbons) from oil palm biomass in Malaysia. Torrefaction is introduced here to enhance the oil palm biomass properties prior to gasification. In this work, the effect of torrefaction on the gasification of three oil palm biomass, i.e., empty fruit bunches (EFB), mesocarp fibres (MF), and palm kernel shells (PKS) are evaluated. Two gasifying agents were used, i.e., CO₂ and steam. The syngas lower heating values (LHV_syngas) for CO₂ gasification and steam gasification were in the range of 0.35–1.67 MJ m⁻³ and 1.61–2.22 MJ m⁻³, respectively. Compared with EFB and MF, PKS is more effective for fuel gas production as indicated by the more dominant emission of light hydrocarbons (CH₄, C₂H₄, and C₂H₆) in PKS case. Gasification efficiency was examined using carbon conversion efficiency (CCE) and cold gas efficiency (CGE). CCE ranges between 4% and 55.1% for CO₂ gasification while CGE varies between 4.8% and 46.2% and 27.6% and 62.9% for CO₂ gasification and steam gasification, respectively. Our results showed that higher concentration of gasifying agent promotes higher carbon conversion and that steam gasification provides higher thermal efficiency (CGE) compared to CO₂ gasification.     

渣油加氢催化剂的工业应用

考察了2种进口渣油加氢催化剂(RM系列和ICR系列)在中化泉州石化有限公司330万t/a渣油加氢装置上的工业应用情况。结果表明:2种渣油加氢催化剂均具有良好的加氢活性;在原料性质和操作条件相近的条件下,与ICR系列催化剂相比,RM系列催化剂的脱硫、脱残炭性能较优,脱金属性能略差,且RM前部反应器床层压差上升速率较慢。     

丁烷氧化反应器装置数据分析与优化

基于丁烷氧化反应器的实际装置数据，经预处理后，采用主成分分析进行数据挖掘。结果表明，可利用该方法来筛选及判断异常数据点，从而可用于反应器状态的实时诊断和预警，同时对反应器输入和输出参数之间的相关性进行分析，理解和把握参数之间的变化特征，发现丁烷转化率与反应器出口的CO/CO2比值呈负相关，体现主反应和副反应的选择性问题，从而可用于指导反应器操作优化等。